ZENITH Ferro Prime

Zenith · Advanced Plant Nutrition

FERRO PRIME

Chelated iron that is still chelated when it reaches the root, on soil where every
other iron source has already failed.

5.0%
ortho-ortho EDDHAof 6.0 % total iron, fully chelated
Fe³⁺
Fe-EDDHA
6.0 % Fe
pH 2–10

ZENITH Ferro Prime product presentation

Calcareous soil can contain iron — while still limiting iron availability.

A calcareous soil can hold several percent iron by weight and still starve the crop. Above pH 7 the ferric
ion oxidises to iron hydroxide, which is effectively insoluble. Roots sit surrounded by iron they cannot
reach, and the grower sees interveinal yellowing on the youngest leaves, short shoots, poor set, and a yield
gap that returns every season.

Broadcasting iron sulphate onto that soil changes nothing: it precipitates within hours of contact. A
chelate is different. It encloses the iron ion in an organic cage and holds it in solution. The only
question that matters is how much pH the cage can take before it lets go.

Fe³⁺ coordination by EDDHA

EDDHA is hexadentate. It grips the ferric ion at six points at once — two phenolate oxygens, two
carboxylate oxygens and two amine nitrogens — which is why calcium cannot displace it in the way it
displaces EDTA at high pH.

Schematic chemical structure of an Fe³⁺–EDDHA chelate complex

Phenolate oxygenthe bond that survives high pH
Amine nitrogencloses the cage around the ion
Carboxylate oxygenkeeps the complex in solution
Aromatic backbonerigid, resists hydrolysis

  • Phenolate oxygen — the bond that survives high pH
  • Amine nitrogen — closes the cage around the ion
  • Carboxylate oxygen — holds the complex in solution
  • Aromatic backbone — rigid, resists hydrolysis

Chelate stability across soil pH

The stability constant is the number to compare. Fe-EDDHA sits around log K 35, against roughly 28 for
DTPA and 25 for EDTA — and because the scale is logarithmic, those gaps are orders of magnitude, not
percentages. In practice the difference shows up as a hard ceiling in soil pH.

Fe-EDDHA chelate stability comparison by soil pH
Fe-EDTA is finished at pH 6.5 and Fe-DTPA at 7.5 — both below the pH at which chlorosis
actually appears. Fe-EDDHA in the ortho-ortho form holds iron in solution to pH 10, which covers the whole
calcareous range.

Specify the EDDHA isomer profile

Manufacturing Fe-EDDHA produces two isomers. Only the ortho-ortho form is fully stable at high pH and
biologically active in the way the label implies; the ortho-para form contributes, then breaks down sooner.
A product that declares total EDDHA alone tells you nothing about the ratio between them — and the ratio is
where the money goes. Ferro Prime declares both.

5.0 % iron chelated by [o,o]-EDDHA
1.0 % [o,p]

The two isomers together are the 6.0 % declared iron. They are not
additional to it.

Total water-soluble iron (Fe)
6.0 % · 60 g/kg
chelated by [o,o]-EDDHA
5.0 % · 50 g/kg
chelated by [o,p]-EDDHA
1.0 % · 10 g/kg
Chelated fraction of declared iron
100 %
Water-insoluble matter
≤ 0.1 %
Chloride
≤ 0.1 %
Chelate stability in soil
pH 2 – 10
Physical form
Dustless microgranulate
Colour
Dark red to near-black
Particle size, d50
0.2 – 1.0 mm
Solubility at 20 °C
≥ 120 g/L
Solubility at 5 °C
≥ 80 g/L
Bulk density
0.65 – 0.85 g/cm³
pH, 1 % solution
7.0 – 9.0

Sodium ferric ethylenediamine bis-(2-hydroxyphenylacetate), CAS
16455-61-1. EU fertilising product under Regulation (EU) 2019/1009, PFC 1(C)(II)(a), mineral single-nutrient
micronutrient fertiliser. Approved for use under the EU Organic Regulation (EU) 2018/848. Professional use
only.

Application rates

Apply where iron deficiency is confirmed, or where calcareous, high-pH soil makes it likely. The lower
figure is preventive, for young plants and sensitive crops; the higher figure corrects visible chlorosis.
On drip and trickle systems reduce by a fifth to a quarter, and split the season’s dose across three
fertigation events or more.

Vines, fruit and berries Young, to first yield Established
Grapevine 3 – 7.5 g/plant 10 – 20 g/plant
Apple, pear 15 – 40 g/plant 40 – 80 g/plant
Apricot, cherry, plum, mirabelle 5 – 30 g/plant 30 – 60 g/plant
Peach 10 – 60 g/plant 60 – 100 g/plant
Raspberry, currant 75 – 150 g/100 m² 150 – 300 g/100 m²
Strawberry 200 – 400 g/100 m² 200 – 400 g/100 m²
Vegetables, ornamentals, nursery Rate Notes
Short-cycle vegetables 60 – 100 g/100 m² Fertigation, as required
Long-cycle and perennial vegetables 75 – 150 g/100 m² Fertigation, as required
Cut flowers 200 – 500 g/100 m² Irrigate at up to 0.2 %
Rose beds, cut up to 750 g/100 m² Split across several irrigations
Nursery stock, area 300 – 500 g/100 m² Establishment phase
Roses, nursery trees, containers 20 – 50 g/plant Or 30 – 60 g per m³ substrate
Hydroponics Product per 1 000 L
1 mg Fe/L ≈ 17 g
1 – 5 mg Fe/L, working range 15 – 80 g
Stock solution max. 7.5 %

Recirculate no more than two or three times a day to limit
oxidation, and keep tanks out of direct sunlight — UV breaks the chelate down.

Using it

Dissolving

Add the microgranules to water that is already moving; never pre-mix them as a dry
blend. Stir for five to ten minutes. Maximum 0.2 % (2 g/L) for direct application, up to 7.5 % for a
stock solution. A correct solution is clear orange-red with nothing settled at the bottom.

Placing it

Soil drench or fertigation to the root zone is the method that works. Broadcast
granules must be watered or cultivated into the top five to ten centimetres straight away. For deep-rooted
perennials, inject the solution into the root-feeding zone under pressure.

Not for foliar use. Fe-EDDHA stains leaves, paths, paving and glasshouse structures
intensely, at concentrations far below the rate that would do any good. Use a foliar-grade iron product
where a leaf application is needed.

Storing it

Frost-free above +2 °C, dry, out of direct light and heat, in the original sealed pack.
The granules take up moisture, so reseal an opened pack at once and use it promptly. Keep on pallets, no
more than two high. Shelf life at least two years sealed.

Supply

1 kg folding carton and 5 kg foil bag in an outer carton. Tariff number 3105 9099 90.
Safety data sheet on request (EUH210). Keep out of reach of children, do not eat, drink or smoke while
handling, and wear respiratory protection where ventilation is poor.

Send us your soil pH and a photograph of the affected crop, and we will tell you whether iron is
actually the problem before you buy anything.

Talk to our agronomy team